what is sublimation ? how does it take place
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What is Sublimation?
The term sublimation is the passage or the transformation or conversion that substances undergo when passing from one state to another, for example from a solid substance to gas.
We can define sublimation as the transition of a substance from the solid phase to the gaseous phase without changing into the liquid phase. This process is an endothermic phase transition that occurs at a temperature and pressure below the triple point of the substance. Desublimation or deposition is the reverse of this process in which a gas is directly converted into solid-state.
Examples of sublimation
- The best example of sublimation is dry ice which is a frozen form of carbon dioxide. When dry ice gets exposed to air, dry ice directly changes its phase from solid-state to gaseous state which is visible as fog. Frozen carbon dioxide in its gaseous state is more stable than in its solid-state.
- Another well-known example of sublimation is naphthalene which is an organic compound. Naphthalene is usually found in pesticides such as mothball. This organic compound sublimes due to the presence of non-polar molecules that are held by Van Der Waals intermolecular forces. At a temperature of 176F naphthalene sublimes to form vapours. It desublimates at cool surfaces to form needle-like crystals.
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Sublimation is the transition of a substance directly from the solid to the gas state, without involving the liquid state.
Sublimation is caused by the absorption of heat which provides enough energy for some molecules to overcome the attractive forces of their neighbors and escape into the vapor phase.
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