What is the difference between photolysis and photochemical reaction
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THERMOCHEMICAL REACTIONS
- These reactions involve absorption or evolution of heat.
- They can take place even in absence of light i.e. dark.
- Temperature has significant effect on the rate of a thermochemical reaction. Temperature has very little effect on the rate of a photochemical reaction.
- The free energy change ∆G of a thermochemical reaction is always negative.
- They are accelerated by the presence of a catalyst.
Photochemical reaction
- These reactions involve absorption of light.
- The presence of light is the primary requisite for the reaction to take place
- Temperature has very little effect on the rate of a photochemical reaction. Instead, the intensity of light has a marked effect on the rate of a photochemical reaction.
- The free energy change ∆G of a photochemical reaction may not be negative.
- Some of these are initiated by the presence of a photosensitizer. However a photosensitizer acts in a different way than a catalyst.
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Anonymous333:
Oh hey soo much for answering my first question ☺☺☺
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