What is the equivalent mass of KMNO4 in neutral and alkaline medium
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In acidic medium: MnO
4
−
+8H
+
+5e
−
→Mn
+2
+4H
2
O
In basic medium: MnO
4
−
+e
−
→MnO
4
2−
In neutral medium: MnO
4
−
+4H
+
+3e
−
→MnO
2
+2H
2
O
Equivalent mass is molecular mass divided by number of electrons gained.
In acidic medium, equivalent weight =
5
Molecularweight
In basic medium, equivalent weight =
1
Molecularweight
In neutal medium, equivalent weight =
3
Molecularweight
Ration of equivalent mass =
5
Molecularweight
:
1
Molecularweight
:
3
Molecularweight
Ratio of equivalent mass =3:15:5
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