What is the hybridisation of H2S2O7?
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In peroxo disulphuric acid, the sulfur atom undergoes sp3 hybridization since, it forms 4 bond pairs.
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H2S2O7 is not an actual distinct molecule. Called oleum, it is a mixture of H2SO4 and SO3. The 1:1 mole ratio is where the formula H2S2O7 comes from, but it is not a distinct molecule, nor does it ionize in water to make H+ and HS2O7^-. Therefore, one cannot really call H2S2O7 an acid in the sense that H2SO4 is an acid.
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