Chemistry, asked by Shahnawaz3519, 1 year ago

what is the hybridization of boron in diborane

Answers

Answered by narayanankanchp7iwot
8
It is sp3 hybridisation
Answered by Anonymous
18
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Boron has three valence electrons so it is supposed to make 3 bonds in a molecule with hybridisation sp2 as only s and two p orbitals are used in hybridisation because last p orbitalis vacant....
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i●●●》》》》》》》》》n case of diborane is different...In diborane bonding of Batom with H and other B is different. Is has two three-center 2-----electron bonds, each one consisting of the twoboron atoms and a hydrogen atom sharing two electrons....

●●●》》》》》》》》The molecule has a total of 12 valence electrons, 3 from each boron atom and 1 from each hydrogenatom. In this molecule each of the two boron atoms will be bonded to two hydrogen atoms via covalent bonds.Thesebonds will use up 8 of the 12 valence electronsThe other 4 valence electrons will be shared by the remaining two hydrogen atoms and by the boron atoms, each atom contributing one orbital to the formation of the 3------center 2----electron bond. Such bond is called banana bond....

■■■■■●●●●●●●●●☆☆☆☆☆☆☆Boron has three valence electrons so it is supposed to make 3 bonds in a molecule with hybridisation sp2 as only s and two p orbitals are used in hybridisation because last p orbitalis vacant.But case of diborane is different. In diborane bonding of Batom with H and other B is different. Is has two three-center 2-electron bonds, each one consisting of the twoboron atoms and a hydrogen atom sharing two electrons.The molecule has a total of 12 valence electrons, 3 from each boron atom and 1 from each hydrogenatom. In this molecule, each of thetwo boron atoms will be bonded to two hydrogen atoms via covalent bonds.Thesebonds will use up 8 of the 12 valence electrons.The other 4 valence electrons will be shared by the remaining two hydrogen atoms and by the boron atoms, each atom contributing one orbital to the formation of the 3-center 2-electron bond. Such bond is called banana bond.
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:::::::::;:Thus 4 orbitals of each boron atom will be hybridised to accommodate are theelectrons (electrons of 2 B-H covalent bonds and shared electrons of 2 banana bonds). Thus hybridisation of boron in diborane is sp3........Thus 4 orbitals of each boron atom will be hybridised to accommodate are theelectrons (electrons of 2 B-H covalent bonds and shared electrons of 2 banana bonds).

》》》》》》》》》》Thus hybridisation of boron in diborane is sp3.....
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