what is the impact of hyperconjugation on dipole moment of any molecule ? explain With example!
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In organic chemistry, hyperconjugation is the interaction of the electrons in a sigma orbital (e.g. C–H or C–C) with an adjacent empty (or partially filled) non-bonding or antibonding σ or π orbital to give an extended molecular orbital. Increased electron delocalization associated with hyperconjugation increases the stability of the system.[1][2][3] Only electrons in bonds that are in the β position can have this sort of direct stabilizing effect—donating from a sigma bond on an atom to an orbital in another atom directly attached to it. However, extended versions of hyperconjugation (such as double hyperconjugation[4]) can be important as well. The Baker–Nathan effect, sometimes used synonymously for hyperconjugation,[5] is a specific application of it to certain chemical reactions or types of structures.
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hyperconjugation is the interaction of the electrons in a sigma orbital (e.g. C–H or C–C) with an adjacent empty (or partially filled) non-bonding or antibonding σ or π orbital to give an extended molecular orbital. Increased electron delocalization associated with hyperconjugation increases the stability of the system.[1][2][3] Only electrons in bonds that are in the β position can have this sort of direct stabilizing effect—donating from a sigma bond on an atom to an orbital in another atom directly attached to it. However, extended versions of hyperconjugation (such as double hyperconjugation[4]) can be important as well. The Baker–Nathan effect, sometimes used synonymously for hyperconjugation,[5] is a specific application of it to certain chemical reactions or types of structures.(6)
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