What is the influence of electronic effects on acidity of carboxylic acids
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Carboxylic acids
In acids, the electron-releasing inductive effect of the alkyl group increases the electron density on oxygen and thus hinders the breaking of the O-H bond, which consequently reduces the ionization. Due to its greater ionization, formic acid (pKa=3.74) is stronger than acetic acid (pKa=4.76).
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