Question

What is the mean of monohalide are dimeric in nature?

Answer 1

Answer:

In a dimer, if the two monomer molecules are similar or identical (i.e. A-A), it is called as homodimer and if the two monomers are different (i.e. A-B), it is called as heterodimer. ... Covalent dimers: When the interaction or chemical bond between two monomers in a dimer is covalent, they are known as covalent dimers.

Answer 2

Monohalide are dimeric in nature:

• A halide that contains only one halogen group is called monohalide.
• Group 16 forms large number of halides. Monohalides, Dihalides, Tetrahalides and hexahalides are the main types of halides.
• Dimer contains two identical, simpler elements/ moleucules.
• In dimer, the monomers are linked by covalent/intermolecular strong or weak bonds.
• Monohalides are dimeric nature because the central atoms (Sulfur and Selenium) are  having empty orbitals which facilitates the dimerization process.
• Example for these are $S_2F_2$, $S_2Cl_2$, $S_2Br_2$  etc.

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