What is the minimum volume of water required to dissolve 1g of calcium sulphate at 298 k?
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Answer:
CaSO4 <=> Ca²+ + SO4²-
Let s is the solubility of CaSO4
then, we know, Ksp = [Ca²+][SO4²-]
Ksp = s.s = s²
A/C to question,
Ksp = 9.1 × 10^-6
so, 9.1 × 10^-6 = s²
s = √{9.1 × 10^-6} = 3.017 × 10^-3 M
so, solubility of CaSO4 = 3.017 × 10^-3 M
= 3.017 × 10^-3 mol/L
= 3.017 × 10^-3 × 136g/L [ weight = molecule weight × mole . and molar weight = 136g/mol]
= 410.3 × 10^-3 g/L
= 0.4103 g/L
it means 0.4103 g CaSO4 is dissolved in 1 L
Therefore, 1g CaSO4 is dissolved in 1/0.4103
= 2.437 L
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