What is the
pH of a solution of
0.28 M acid and
0.84 M of its conjugate base. If the ionization
constant of acid is
4 x 10-4
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1
Answer:
Let’s assume that the acid you are referring to is HA and therefore the conjugate base is A-. Then, the equilibrium we are considering is:
HA = H+ + A-
and therefore the ionization expression is:
Ka = [H+]{A-]/[HA]
Rearrange this and solving for [H+] gives
[H+] = Ka*[HA]/[A-]
Putting in the numbers given:
[H+] = 4*10^-4 * (0.28)/(0.84)
[H+] = 1.32 * 10^-4
Then, remembering that
pH = -log[H+] then
pH = -log (1.32 * 10^-4) = 3.88
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