What is the pH of the buffer 0.10 M Na2HPO4/0.15 M KH2PO4?
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Hydrogen phosphate ion is a weak base so it ionizes incompletely in water to dihydrogen phosphate ion and hydroxide ion.
The dissociation of hydrogen phosphate ion is represented by equation shown below;
The expression for the base dissociation constant of is;
…… (1)
We have. To calculate pH of the buffer solution, assume x M of hydrogen phosphate ion dissociates to form x M of hydroxide ion.
Construct ICE table and obtain the equilibrium concentrations as shown below:
Initial (M)
Change (M)
Equilibrium (M)
Explanation:
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