What is the relation between Cp and Cv for 2 moles of an ideal gas ?
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Answers
Answered by
113
Cp - Cv = R
This is a standard relation for one mole. For two moles the difference will be = 2 R.
In general Cp - Cv = n R ---- (0)
============
We know PV = n R T, V = (nR/P) * T --- (1)
At constant pressure, ΔV/ΔT = nR/P --- (2)
From first law of thermodynamics, we have that
ΔQ = ΔU + W = ΔU + P ΔV ---- (3)
We know that the internal energy U and the change in it ΔU, are entirely dependent on the temperature for the same amount of substance. So it does not depend on the pressure or volume.
Cp = [ ΔQ/ΔT ]_P=const
= [ ΔU/ΔT ]_P=const + P * [ ΔV/ΔT ]_P=const
= ΔU/ΔT + P * n R/P = ΔU/ΔT + n R
Cv = [ ΔQ/ΔT ]_V=const
= [ ΔU/ΔT ]_V=const + P [ ΔV/ΔT ]_V=const
= ΔU/ΔT + 0
Hence Cp = Cv + n R
This is a standard relation for one mole. For two moles the difference will be = 2 R.
In general Cp - Cv = n R ---- (0)
============
We know PV = n R T, V = (nR/P) * T --- (1)
At constant pressure, ΔV/ΔT = nR/P --- (2)
From first law of thermodynamics, we have that
ΔQ = ΔU + W = ΔU + P ΔV ---- (3)
We know that the internal energy U and the change in it ΔU, are entirely dependent on the temperature for the same amount of substance. So it does not depend on the pressure or volume.
Cp = [ ΔQ/ΔT ]_P=const
= [ ΔU/ΔT ]_P=const + P * [ ΔV/ΔT ]_P=const
= ΔU/ΔT + P * n R/P = ΔU/ΔT + n R
Cv = [ ΔQ/ΔT ]_V=const
= [ ΔU/ΔT ]_V=const + P [ ΔV/ΔT ]_V=const
= ΔU/ΔT + 0
Hence Cp = Cv + n R
Answered by
11
Answer:
Explanation:
H=u+pv
H=u+mrt
dh=dut+mrdt
Mcpdt=mcvdt+mrdt
Cp=cv+r
Cp-cv=r
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Math,
7 months ago
= ΔU/ΔT + P * n R/P = ΔU/ΔT + n R
Cv = [ ΔQ/ΔT ]_V=const
= [ ΔU/ΔT ]_V=const + P [ ΔV/ΔT ]_V=const
= ΔU/ΔT + 0