what is the role of voids in solubility.how can you explain unchanged volume of solvent when solute is dissolved in it on the basis of voids
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Answer:
Solubility is defined as the upper limit of solute that can be dissolved in a given amount of solvent at equilibrium. In such an equilibrium, Le Chatelier's principle can be used to explain most of the main factors that affect solubility. Le Châtelier's principle dictates that the effect of a stress upon a system in chemical equilibrium can be predicted in that the system tends to shift in such a way as to alleviate that stress.
Solute-Solvent Interactions Affect Solubility
The relation between the solute and solvent is very important in determining solubility. Strong solute-solvent attractions equate to greater solubility while weak solute-solvent attractions equate to lesser solubility. In turn, polar solutes tend to dissolve best in polar solvents while non-polar solutes tend to dissolve best in non-polar solvents. In the case of a polar solute and non-polar solvent (or vice versa), it tends to be insoluble or only soluble to a miniscule degree. A general rule to remember is, "Like dissolves like."
Common-Ion Effect
The common-ion effect is a term that describes the decrease in solubility of an ionic compound when a salt that contains an ion that already exists in the chemical equilibrium is added to the mixture. This effect best be explained by Le Chatelier's principle. Imagine if the slightly soluble ionic compound calcium sulfate, CaSO4, is added to water. The net ionic equation for the resulting chemical equilibrium is the following:
CaSO4(s)⇌Ca2+(aq)+SO2−4(aq)(1)
Calcium sulfate is slightly soluble; at equilibrium, most of the calcium and sulfate exists in the solid form of calcium sulfate.
Suppose the soluble ionic compound copper sulfate (CuSO4) were added to the solution. Copper sulfate is soluble; therefore, its only important effect on the net ionic equation is the addition of more sulfate (SO42-) ions.
CuSO4(s)⇌Cu2+(aq)+SO2−4(aq)(2)
The sulfate ions dissociated from copper sulfate are already present (common to) in the mixture from the slight dissociation of calcium sulfate. Thus, this addition of sulfate ions places stress on the previously established equilibrium. Le Chatelier's principle dictates that the additional stress on this product side of the equilibrium results in the shift of equilibrium towards the reactants side in order to alleviate this new stress. Because of the shift toward the reactant side, the solubility of the slightly soluble calcium sulfate is reduced even further.
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