What is the significance of the 'isolated gaseous Aron's while defining the ionization enthalpy?
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It is because of this reason the term 'isolated gaseous atom' has been included in definition of ionisation enthalpy and electron gain enthalpy. The term 'ground state' here means that the atom must be present in the most stable state, i.e., the ground state.
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Ground state of an atom refers to the most stable state of an atom. If an isolated gaseous atom is in its ground state, then less amount energy would be required to remove an electron from it.
For this reason, the term 'isolated gaseous atom' is used in the definition of ionization enthalpy.
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