What is the van't hoff factor which undergo tetramerization?
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In case of association i (van’t Hoff factor) is given by
i = 1 – (1- 1/n)α, where
n= number of molecules associates = 4 (here),
α = fraction of molecules associates
i = 1 – (1- ¼)α = 1 – ¾ α
if α be 1 (complete association), then
i= 1 – ¾ = ¼
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Answer:
Vant's hoff factor = Totalnumberofmolesafterdissociationtotalnumberofinitialmoles
K4[Fe(CN)6]=4K++[Fe(CN)6]4−
∴ vant's hoff factor = 5
Because total number of ions after dissociation is 5
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