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Precipitation is the process of transforming a dissolved chemical substance into an insoluble solid from a super-saturated solution. When the reaction occurs in a liquid solution, the solid formed is called the precipitate.
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Distillation refers to the selective boiling and subsequent condensation of a component in a liquid mixture. It is a separation technique that can be used to either increase the concentration of a particular component in the mixture or to obtain (almost) pure components from the mixture.
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