What is water gas equilibrium reaction?
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The water-gas shift reaction is an equilibrium process: CO +H2O(g) ↔ CO2 +H2 [R1. 6]. The forward reaction is exothermic (ΔH°R=−41.0 MJ/kmol), converting carbon monoxide and steam to hydrogen and carbon dioxide. The forward reaction is active at temperatures lower than 700°C.
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K=
[H
2
O(g)]
[CO(g)][H
2
(g)]
Concentration will increase, on halving the volume. There are two terms in numerator. So to keep K constant, concentration of [H
2
O] should increase
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