WHAT VARIABLE SHOULD MARCUS CHANGE IN HIS EXPERIMENT
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Answer:
Have to change the charges in marcus experiment.
Explanation:
- Charges are rearranged as a result of an electron transfer, which significantly affects the solvent environment.
- As a result, the atoms and electrons in the dipolar solvent molecules are rearranged in the direction of the field of charges (a process known as orientation polarisation) (atomic and electron polarization, respectively).
- The free energy of activation and, thus, the reaction rate are determined by the solvent polarisation.
- In addition to the structural changes mentioned above, substitution, elimination, and isomerization reactions differ from outer sphere redox reactions in that the nuclei's motions and the shifting of charges (charge transfer, CT) occur continuously.
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Answered by
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Answer: Have to change the charges in Marcus' experiment.
Explanation:
- Charge rearrangement as a result of electron transfer has a significant effect on the solvent environment.
- As a result, the atoms and electrons in dipolar solvent molecules rearrange in the direction of the charge field (a process known as orientational polarization) (atomic and electronic polarization, respectively).
- Gibbs activation energy, and hence reaction rate, is determined by solvent polarization.
- In addition to the structural changes described above, substitution, elimination, and isomerization reactions differ from outer-sphere redox reactions in that core motion and charge transfer (CT) are continuous.
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