Question

What was the Earth’s second atmosphere probably like, and what was its origin?

Answer 1

The atmosphere is a collection of gases, and constitutes the air we breathe. The air we breathe today is made mostly of N2 and O2, but also H, He, H2O, CO2, SO2, methane, ammonia, and many other gases including smog from human activities. Scientists think that the atmosphere we breathe today is nothing like the atmosphere the Earth started with. In fact scientists think that 99% of today's atmosphere is new compared to the original air. Thus scientists call the atmosphere of today a secondary atmosphere.

Scientists think that the secondary atmosphere came from the many volcanic eruptions which took place in Earth's early history, and which continue today. All volcanoes are different but in general they release gases such as H2O, CO2, SO2, H2S, HCl, N2, NO2. These gases come from the melting of the Earth's crust at subterranian depths. In fact, volcanic activity can be thought of as recycling and replenishing the molecules of the atmosphere. These molecules are not the Nitrogen and Oxygen which are the majority of gases in the air today, however.

The formation of the early ocean played a large part in shaping what gases remained in the atmosphere and what gases were carried into the water, to become a part of the ocean and surface. Scientists think that the Earth's secondary atmosphere may have come to be dominated by N2 because it alone of all the gases comprising the secondary atmosphere does not readily dissolve in water. Oxygen came into the atmosphere as a waste product from the photosynthetic activity of early life forms after that oxygen had first combined with residual surface iron to produce iron ore. 

Answer 2

Gases produced were probably similar to those created by modern volcanoes (H2O, CO2, SO2, CO, S2, Cl2, N2, H2) and NH3 (ammonia) and CH4 (methane)

No free O2 at this time (not found in volcanic gases).

Ocean Formation - As the Earth cooled, H2O produced by out gassing could exist as liquid in the Early Archean, allowing oceans to form.

Evidence - pillow basalts, deep marine seds in greenstone belts.