What will be the effect on solubility of the precipitate
if pH is decreased, when anion of the salt is the
conjugate of weak acid
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Temperature will be the effect on solubility of the precipitate
if pH is decreased, when anion of the salt is the
conjugate of weak acid
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The solubility of the precipitate is increased if the pH is decreased when anion of the salt is the conjugate of a weak acid.
- The anion of a salt that is a conjugate of a weak acid itself acts as a strong base.
- When such a solution is subjected to a change in its pH, the solubility of the precipitate changes.
- Let the reaction be XA ⇔ X⁺ + A⁻
- A decrease in pH means that the solution becomes more acidic. The equilibrium then according to Le Châtelier's Principle shifts in the forward direction to make the solution basic.
- Due to this, more XA will get dissolved.
- Here, XA is the salt, X⁺ is the cation and A⁻ is the anion of the salt is the conjugate of a weak acid.
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