What will be the enthalpy of the given isomerisation process?
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What is the enthalpy change for the isomerization reaction of ethanol to dimethyl ether?
The two heats of formation are:
2 C +12O2+ 3 H2 → C2H5OH (ethanol = ΔH∘f =-277.6 kJ/mol )
2 C +12O2 + 3 H2 → CH3OCH3 (dimethyl ether = ΔH∘f = -203.3 kJ/mol)
So, for the reaction:
C2H5OH → CH3OCH3
The enthalpy of isomerization would be:
ΔHrxn = ΔHprod - ΔHreact
ΔHrxn = [-203.3 kJ/mol] - [-277.6 kJ/mol] = 74.3 kJ/mol
This reaction is endothermic.
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