what would be the half reactions and voltage if graphite rod was cathode and zinc was anode?
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The zinc loses two electrons to form Zn2+. The half-reaction on the cathode where reduction occurs is Cu2+ (aq) + 2e- = Cu(s). ... These batteries have a zinc container that is the anode that is filled with a paste of MnO2, graphite and NH4 Cl. They have a carbon rod going down their middle, which is the cathode.
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By convention in standard cell notation, the anode is written on the left and the cathode is written on the right. So, in this cell: Zinc is the anode (solid zinc is oxidised). Silver is the cathode (silver ions are reduced).
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