Whats js equilibrium conc of each of the substances in the equilibrium when initial conc of icl was 0.78m?
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2ICl (g) <=> I2(g) + Cl2(g) ; Kc = 0.14
at t = 0
conc. of ICl = 0.78 M
conc. of I2 = 0 M
conc. of Cl2 = O M
at equilibrium ,
conc. of ICl = (0.78 - 2x ) M
conc. of I2 = x M
conc. of Cl2 = x M
now, Kc = [I2][Cl2]/[ICl]²
Kc = x.x/(0.78 - 2x )²
0.14 = x²/(0.78 - 2x )²
take square root both sides,
√0.14 = x/(0.78 - 2x )
0.374 = x/(0.78 - 2x )
x = 0.29172 - 0.748x
1.748x = 0.21972
x = 0.29172/1.748 = 0.1668 ≈ 0.17
hence, conc. of ICl at equilibrium = 0.78 - 0.34 = 0.44 M
conc. of I2 = x = 0.17 M
conc. of Cl2 = x = 0.17 M
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