When 0.1 mol ch3cooh is present in a litre solvent?
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Answer:
CH3COOH⇌CH3COO⊝+H⊕
at t=0 0.1 0 0
at eqm 0.1−C C C
now, i=0.1−C+C+C=0.1+C
ΔTb=iKf×m
⇒0.75=(0.1+C)×5×0.1 [Since M≃m=0.1]
∴ dissociation constant= 5×10−2
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