When 0.2 g of butan-1-ol was burnt in a suitable apparatus,
the heat evolved was sufficient to raise the temperature
of 200 g of water by 5°C. Then what will be enthalpy of combustion of butan-1-ol in kcal/mol ?
Note :-
Molar mass of butan-1-ol is 74
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Solution:- (D) 370
Heat required to raise the temperature of 200g water by 5℃(q)=m.c.ΔT
whereas,
m= mass of water =200g
c= specific heat of water =1Cal−g/℃
ΔT=5℃
∴q=200×1×5=1 kcal
Heat liberated by 0.2g of 1-butanol on burning =1 kcal
∴ Heat liberated by 1 mole of 1-butanol (74g)=
0.2
1
×74=370 kcal
Hence the heat liberated is 370 kcal.
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