When during electrolysis of a solution of,9650 coulmobs of charge pass through the electroplating bath, the mass of silver deposited on the cathode will be:
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here, no. of moles of electrons = Q/F=9650/96500=0.1mole
Here, no. of moles of electrons = FQ=965009650=0.1mole
Now,
1 mole of AgNO3 will produce one mole of monovalent silver ion on dissociation.
Therefore,
The number of electrons involved will also be one mole for one mole of AgNO3.
Thus, 0.1 moles of silver will be produced by 0.1 mole of AgNO3 .
Since,
Silver nitrate dissociates completely into Ag+ and NO3− ion.
Hence,
Mass of silver = no. of moles x molar mass= 0.1 x 108 = 10.8 g
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