When sulpher vacancy of pure zns red shifted when metal ferrite added?
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=> This effect is explained by the filling of sulfur vacancies. The ZnS luminescence is quenched with an activation energy of 62 meV, which is assigned to the detrapping of a bound hole from such a vacancies.✨✨✨
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Density functional theory calculations confirmed that the reactive sulfur dioxide molecules that dissociated from TFSI can be reduced to sulfur and oxygen gas at the vacancy site to form strongly bound S-Mo. Our results reveal how defect-mediated nonradiative recombination can be effectively eliminated by a simple chemical treatment method, thereby advancing the practical applications of monolayer semiconductors.
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