Chemistry, asked by ruhanithakur, 1 year ago

when the iron cr2 O72- acts as an oxidant in acidic aqueous solution the ion Cr3+ is formed how many moles of Sn2+ would be oxidised to Sn4+ by 1 mole of Cr2O72- ions


siril: it cannot be 'accident'....it is probably 'oxidant'
siril: although the answer is 3
ruhanithakur: yes.. i know it is oxidant. accident typed by mistake
ruhanithakur: please solve this problem

Answers

Answered by siril
18
    Sn⁺²  +  Fe⁺²Cr₂O₇⁻² ---------------->  Fe⁺²  +  Cr⁺³  +  Sn⁺⁴

Change in oxidation state of Sn⁺² is 4 - 2 = 2 = n-factor
 
Change in oxidation state of Cr⁺³ for 2 atoms is 2(6 - 3) = 2(3) = 6 = n-factor

In any reaction, "moles x n-factor" must be same on both sides of reaction.

         
  1 x 6 = n moles x 2
                 6  = n x 2
                  n = 3

Therefore 3 moles of Sn⁺² can be oxidized by 1 mole of Cr₂O₇⁻²
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