Question

Which form of the dimethylcyclohexane is obtained in enantiopure form?

Answer 1

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Answer 2

Answer:

The enantiopure form is trans 1,2-dimethylcyclohexane.

Explanation:

• In the preferred chair, both methyl are equatorial, which lowers 1,3-diaxial repulsions.
• Only the trans-isomer, which is 6 kJ/mol more stable than the cis-isomer, is possible in the 1,2-disubstituted situation (in the 1,2-cis isomer one of the methyl groups must be axial)

• Enantiopure refers to a substance that produces only one isomer as a product. If a product has two or more isomers, one of them is the main isomer.

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