Question

Which has more boiling point bromoform or dibromomeghane?

Answer 1

Answer:

For alkyl halides containing the same alkyl group, the boiling point increases with an increase in the atomic mass of the halogen atom. ... Therefore, the boiling point of Dibromomethane is higher than that of chloromethane and bromomethane, but lower than that of bromoform.

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Answer 2

For alkyl halides containing the same halide, the boiling point increases with an increase in the size of the alkyl group. Thus, the boiling point of 1-chlorobutane is higher than that of isopropyl chloride and 1-chloropropane. Further, the boiling point decreases with an increase in branching in the chain.