Which is more basic pch30c6h4nh2 or pno2c6h4(ch2nh2)?
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pno2c6h4(ch2nh2)
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It's the second one, since resonance of nitrogen lone pair is not possible with benzene as there's no conjugation between the two. While in the first one there's conjugation leading to resonance which decreases it's basicity.
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