Which is more sharp vibrational rotaional and elecronics spectra?
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electronic Spectra is more sharp than vibrational rotational
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here is ur answer mate...
Centrosymmetric linear molecules have a dipole moment of zero, so do not show a pure rotation spectrum in the infrared or microwave regions. On the other hand, in certain vibrational excited states the molecules do have a dipole moment so that a ro-vibrational spectrum can be observed in the infrared
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