Which of the following is the most stable diene ? Explain (ans is d q314)
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hey mate here is your answer
i guess it is (b) , (c)
because compunds with alternate double bonds are more stable than other compounds
hope it may help you
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Answer:
The trans-1,3 pentadiene is most stable among the given dienes.
Therefore the option (c) is correct.
Explanation:
- The stability of diene depends upon the conjugation. More the delocalization of electron density , more the conjugation. Therefore more the stability of diene.
- Among the given options the structure (a) has no conjugation. The structure (d) is not a diene, because a diene has two double bond in it.
- While option (c) is cis 1,3-pentadiene and option (d) is trans 1,3- pentadiene, They both are diene and have conjugation.
- But trans 1,3- pentadiene is more stable than cis 1,3-pentadiene because cis 1,3-pentadiene has unfavorable steric hindrance between the bulky groups. on the other hand in trans 1,3- pentadiene both bulky groups are on opposite sides.
Therefore trans 1,3- pentadiene is most stable.
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