Which of the following statements is incorrect?
1) The O–O bond length in H2O2 is larger than that in O2F2
2) The O–O bond length in H2O2 is slightly smaller than that in O2^2-
3) O2^2-and O2^2+ species are paramagnetic and have same number of unpaired electron
4) None of the above
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Answer:
ANSWER IS NO3
Explanation:
BECAUSE U KNOW IT
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The statement that is incorrect is "the O–O bond length in H2O2 is slightly smaller than that in O2^2-" (option 2).
- The O-O bond length in H2O2 is actually slightly longer than that in O2^2- rather than slightly smaller. This is because the two oxygen atoms in H2O2 are both bonded to a central hydrogen atom, which introduces steric repulsion and weakens the O-O bond.
- In contrast, the two oxygen atoms in O2^2- are bonded to two highly electronegative atoms, which strengthens the O-O bond.
- Statement 1 is true as the electronegativity of fluorine is greater than oxygen, leading to a shorter O-O bond length in O2F2 than in H2O2.
- Statement 3 is also true as both O2^2- and O2^2+ have two unpaired electrons, making them paramagnetic.
- In summary, the correct answer is 2) The O–O bond length in H2O2 is slightly smaller than that in O2^2-.
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