Which of the two nh3 or nf3 has higher dipole moment?
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But, NH3 has more dipole momentthan NF3. In NH3, N is more electronegative than H. So, N pulls the electrons from H towards itself and so, the direction of moment due to the N-H bonds is in the same direction as that of the lone pair of electrons on Nitrogen.
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❤.In NH3, the directionof the orbital dipole moment due to lone pair is in the same direction of the 'resultant dipolemoment' of the 3N-H bonds.
❤.Hence,the net dipole moment of NH3 is positive.
❤. But in NF3, molecule the direction of the orbital dipole moment due to lone pair is in the opposite direction to the 'resultant dipole moment'of the 3 N-F bonds.
❤.Hence, its net dipole moment decreases.
❤. Therefore,dipole moment of NH3 is greater than that of NF3
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