Which of these is the rate-determining step in the sulfonation of benzene?
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Formation of arrenium ion is the rate determining step of sullhonation of benzene.
Explanation:
- The benzene is a very stable molecule that has all the carbons sp2 hybrid.
- Sulphuric acid is the reagent which actually forms the sulphur trioxide gas which acts as the electrophile.
- This electrophile attacks the sp2 hybrid carbon with its vacant orbital to take the pi bond electrons.
- This forms the sulphonium ion which is also called as the arrenium ion.
- This then leads to the elemination of hydrogen ion from the carbon restoring sp2 hybridization and thereby aromaticity.
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Answer:
bromination step 3 formation of arenium ion is rate determining
nitration step 2 attack of electrophile is rate determining
sulphonation step 1 formation of arenium ion is rate determining
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