Chemistry, asked by MRahul6303, 10 months ago

Which one of the following statements is correct for shape selective catalysts? a]The catalytic reaction does not depend upon the pore structure of the catalyst b]Zeolites are not shape selective catalysts because of their honeycomb like structure. c]Shape selective catalysts are microporous aluminosilicates with 3D network of silicate d]ZSM-5 is a shape selective catalyst which converts alcohol into acids.

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Answered by angels75
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Chemistry

Surface Chemistry

Catalysis

Which one of the following ...

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Asked on December 30, 2019 by

Monisha Krish

Which one of the following statements is not correct about zeolites?

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ANSWER

The catalytic reaction that depends upon the pore structure of the catalyst and the size of the reactant and product molecules is called shape-selective catalysis. Zeolites are good shape-selective catalysts because of their honeycomb-like structures. An important zeolite catalyst used in the petroleum industry is ZSM-5. It converts alcohol directly into gasoline (petrol).

This is because of the following:

(A) Zeolites are natural ion exchangers. They take up calcium ions from hard water and release sodium ions in water. Hence, they act as water softeners. Hence, option A is correct.

(B) Zeolites trap small molecules (such as water, ammonia and carbon dioxide) in their interstices reversibly. Hence, they act as molecular sieves. Thus, option B is not correct.

(C) Zeolites are complex oxide catalysts commonly used in petrochemical industries. Hence, option C is correct.

(D) The activity of zeolites is increased by heating them in a vacuum. Hence, option D is correct

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