Chemistry, asked by pratiksha20, 1 year ago

who is more basic in aniline and methylamine?

Answers

Answered by Anonymous
1
Methylamine is more basic because
The reason given for the question is that in aniline the lone pair on N atom is delocalized throughout the benzene ring, making it less available for donation.
Answered by MajorLazer017
2

\huge\textcolor{orange}{\texttt{Answer :-}}

The strength of a base or an alkaline solution is determined by the pK_b value. The lower the pKb value, the stronger the base. In the case of methylamine and aniline, aniline has more pK_b value. Hence, aniline is less basic than methylamine. This happens because :

In aniline, the lone pair of electrons on N atom is delocalized over the benzene ring. As a result, electron density on the nitrogen decreases.

On the other hand, in CH_3NH_2, + I effect of CH_3 group increases the electron density on N atom.

Therefore, aniline is less basic than methylamine and hence pK_b of aniline is higher than that of methylamine and aniline is less basic than methylamine.

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