Why 2nd electron affinity is positive ?
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The 2nd electron affinity is defined as the enthalpy change for: Because the electron is negatively charged you can see that there will be repulsion between the ion and the electron making the process endothermic, hence the positive value.
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However, more energy is required to add an electron to a negative ion (i.e., second electron affinity) which overwhelms any the release of energy from the electron attachment process and hence, second electron affinities are positive
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