Why among isomeric primary secondary and tertiary amines primary amines have highest boiling point whereas tertiary amines have least
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Alcohols have higher polarity as compared to amines and hence, they form stronger intermolecular hydrogen bonds. ... In tertiary amines, there is no intermolecular association due to the absence of free hydrogen atom for bonding. The order of boiling point of amines is as follows: Primary > Secondary > Tertiary.
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