Why an electrolyte be dissolved in pure water only for electrolysis?
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Answer & Explanation
Electrolysis is defined as a process of decomposing ionic compounds into their elements by passing a direct electric current through the compound in a fluid form. The cations are reduced at cathode and anions are oxidised at the anode. For example, acidified or salt-containing water can be decomposed by passing electric current to their original elements hydrogen and oxygen. Molten sodium chloride can be decomposed to sodium and chlorine atoms.
Electrolyte for water electrolysis Care must be taken in choosing an electrolyte since an anion from the electrolyte competes with the hydroxide ions to give up an electron. An electrolyte anion with less standard electrode potential than hydroxide will be oxidized instead of the hydroxide, and no oxygen gas will be produced.
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