why anode is negative in Daniel cell
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ANSWER :
Anode is negative in Daniel cell because of oxidation of the electrode for the given interphase of Electrode and Electrolyte
Explanation:
For example take a Daniel cell, due to E(Reduction potential) of Zn is lower than Cu, the Electrode made up of Zn Oxidises , i.e, the electrode loses Zn in the form of Zn^+2 ions into electrolyte. This leads to accumulation of electrons on the Anode making it Negatively Charged.
TIPS: For Electrochemical cell ,
LOAN - LEFT OXIDATION ANODE NEGATIVE
For Electrolytic cell,
POA - POSITIVE OXIDATION ANODE
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- Daniel cell is an example of galvanic or electrochemical cell.
- It is basically Zn-Cu cell.
- The anode is the oxidation half of the cell.
- It is taken as negative. Here, Zn oxidises to Zn^+2 and two electrons.
- The cathode is the reduction half of the cell.
- It is taken as positive because here Cu^+2 reduces to Cu.
- Also a salt bridge is taken in middle
- It maintains electrical neutrality of cells.
- It completes the current by allowing flow of electrons.
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