Question

Why are aryl halides less reactive towards nucleophilic substitution?

Answer 1

Answer:

yes aryl halides are less nucleophillic towards nucleophillic substitution.

Explanation: because of                                                                                                         1:because of formation of carbanion.                                                                               2:because of repulsion between incoming nucleophile and benzene ring because both are electron rich in species.                                                                               3:and less stabilised intermediate.

Answer 2

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ANSWER :

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Aryl halides are less reactive towards nucleophilic substitution reaction as compared to alkyl halides due to resonance stabilization.

Due to resonance, C−Cl bond acquires partial double bond character and becomes shorter and stronger and cannot be easily replaced by nucleophiles. 

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