why are aryl halides less reactive towards nucleophilic substitution reactions than alkyl halides?
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Answered by
3
hey buddy !! here's your answer...
Aryl halides are relatively unreactive towards nucleophilic substitution reactions as compared to alkyl halides.
This lack of reactivity is due to several factors.
➡️Steric hindrance caused by the benzene ring of the aryl halide prevents SN2 reactions.
➡️ Moreover, phenyl cations are unstable, thus making SN1 reactions impossible.
hope it helps !! ❤️✌️
Aryl halides are relatively unreactive towards nucleophilic substitution reactions as compared to alkyl halides.
This lack of reactivity is due to several factors.
➡️Steric hindrance caused by the benzene ring of the aryl halide prevents SN2 reactions.
➡️ Moreover, phenyl cations are unstable, thus making SN1 reactions impossible.
hope it helps !! ❤️✌️
Answered by
1
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ANSWER :
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Aryl halides are less reactive towards nucleophilic substitution reaction as compared to alkyl halides due to resonance stabilization.
Due to resonance, C−Cl bond acquires partial double bond character and becomes shorter and stronger and cannot be easily replaced by nucleophiles.
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