Why are highlights of beryllium polymeric?
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The charge distribution shows an electron drift of approximately 0.15 electrons fromberyllium to the hydrogen atoms. The total energy calculation indicates thatpolymeric beryllium hydride is more stable than the monomer while polymericboron hydride is less stable than the monomeric species.
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Because of this, they are unstable. So, in order to attain stability they polymerise to make long chains. They do this by forming coordinate bonds (dative covalent bonds) between lone pairs on halide atoms and adjacent beryllium atoms.
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