Question

Why are lone pair-lone pair repulsions stronger than lone pair-bond pair?

Answer 1

The bonding electron pair shared in a sigma bond with an adjacent atom lies further from the central atom than a nonbonding (lone) pair of that atom, which is held close to its positively charged nucleus. VSEPR theory therefore views repulsion by the lone pair to be greater than the repulsion by a bonding pair.

Answer 2

The bonding electron pair shared in a sigma bond with an adjacent atom lies further from the central atom than a nonbonding (lone)pair of that atom, which is held close to its positively charged nucleus. VSEPR theory therefore views repulsion by the lone pairto be greater than the repulsionby a bonding pair.

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