Why are the colours of flames different for different substances?
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When you heat an atom, some of its electrons are "excited* to higher energy levels. When an electron drops from one level to a lower energy level, it emits a quantum of energy. ... The different mix of energy differences for each atom produces different colours. Each metal gives a characteristic flame emission spectrum
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Flame colour may be different for different substances because on burning they emit waves of different wavelength due to differences in their atomic structures. This is actually a characterstic property of materials. For example, Sodium on burning emits a yellow flame while Potassium emits a lilac flame.
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