Why boiling point of ortho dichlorobenzene is more?
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Answer: Dichlorobenzene has higher melting point then o and m isomers because it is more symmetric in structure and fits perfectly in crystal lattice. As a result, inter-molecular forces of attraction are stronger and therefore, greater energy is required to break its lattice and its melts at higher temperature.
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because chlorine has high electronegativity which causes to pull the atoms more
there fore boiling point is more
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