Why conductance is high of hydrogen ion and less that of hydroxyl ion?
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Water molecule rotation, (b) hopping, and (c) new proton position. Because of their high molar conductivity, the hydrogen ions will often dominate the conductance found. Because of electroneutrality, there are equal numbers H+ and Cl− when the strong acid, hydrochloric acid (HCl), dissociates.
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H+ has an exceptionally high conductivity. At least when compared to the ideally predicted values.
This phenomenon can be explained with an understanding of the Grotthuss Mechanism. According to this explanation, the proton diffuses through the hydrogen bond network of the water molecules. The H+ basically is relayed along a chain of water molecules.
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