why CP is greater than CV
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The heat capacity at constant pressure CP is greater than the heat capacity at constant volume CV, because when heat is added at constant pressure, the substance expands and work.
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The heat capacity at constant pressure CP is greater than the heat capacity at constant volume CV, because when heat is added at constant pressure, the substance expands and work.
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What is Cp and Cv ?
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☑Cp is the specific heat at constant pressure .
☑Cv is the specific heat at constant volume
Now ,
What is specific heat ?
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☑Amount of heat that required to raise the temperature by 1°C .
Why Cp is always greater than Cv?
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As Cp is amount of heat that required to raise the temperature by 1°C when heat is given at constant pressure.
So pressure is fixed in Cp but some work may be done . So heat may produce.
But ,
Cv is the amount of heat that required to raise the temperature by 1°C when heat is given at constant volume.
According to the equation
W = P∆V
if volume is constant then workdone is Zero . So no heat produced .
Result
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So we get that Cp > Cv
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